ASTM C781-20 - 1.6.2020
 
Significance and Use

4.1 Property data obtained with the recommended test methods identified herein may be used for research and development, design, manufacturing control, specifications, performance evaluation, and regulatory statutes pertaining to nuclear reactors that utilize graphite.

4.2 The referenced test methods are applicable primarily to specimens in the non-irradiated and non-oxidized state. Testing irradiated specimens often requires specimen geometries that do not meet the requirements of the standard. Specific instructions or recommendations with respect to testing non-conforming geometries can be found in STP 15784 and/or Guide D7775. When testing irradiated specimens at elevated temperatures, the effects of annealing should be considered (see Note 1).

Note 1: Exposure to fast neutron radiation will result in atomic and microstructural changes to graphite. This radiation damage occurs when energetic particles, such as fast neutrons, impinge on the crystal lattice and displace carbon atoms from their equilibrium positions, creating a lattice vacancy and an interstitial carbon atom. The lattice strain that results from displacement damage causes significant structural and property changes in the graphite and is a function of the irradiation temperature and dose. When the temperature of the graphite is brought above the temperature at which it was irradiated, enough energy is provided that the structure of the graphite will anneal back to its original condition. Therefore, measurement techniques that bring the specimen temperature above the irradiation temperature can result in property values that change during the measurement process. For this reason, measurements made on irradiated test specimens below the irradiation temperature will produce results that are representative of the irradiation damage. However, measurements made at temperatures above the irradiation temperature could include the effects of annealing.

4.3 Additional test methods are in preparation and will be incorporated. The user is cautioned to employ the latest revision.

 
1. Scope

1.1 This practice covers the application and limitations of test methods for measuring the properties of graphite materials. These properties may be used for the design and evaluation of gas-cooled reactor components.

1.2 The test methods referenced herein are applicable to materials used for replaceable and permanent components as defined in Section 7 and includes fuel elements; removable reflector elements and blocks; permanent side reflector elements and blocks; core support pedestals and elements; control rod, reserve shutdown, and burnable poison compacts; and neutron shield material. Specific aspects with respect to testing of irradiated materials are addressed.

1.3 This practice includes test methods that have been selected from ASTM standards and guides that are specific to the testing of materials listed in 1.2. Comments on individual test methods for graphite components are given in Section 8. The test methods are summarized in Table 1.

1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D5600-22

Standard Test Method for Trace Metals in Petroleum Coke by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES)

C1039-85(2020)e1

Standard Test Methods for Apparent Porosity, Apparent Specific Gravity, and Bulk Density of Graphite Electrodes (Includes all amendments and changes 12/7/2020).

C1233-15(2021)

Standard Practice for Determining Equivalent Boron Contents of Nuclear Materials

C1274-12(2020)

Standard Test Method for Advanced Ceramic Specific Surface Area by Physical Adsorption

D346-04

Standard Practice for Collection and Preparation of Coke Samples for Laboratory Analysis

D1193-06(2018)

Standard Specification for Reagent Water

D2854-09(2019)

Standard Test Method for Apparent Density of Activated Carbon

D2862-16(2022)

Standard Test Method for Particle Size Distribution of Granular Activated Carbon

D3104-14a(2018)

Standard Test Method for Softening Point of Pitches (Mettler Softening Point Method) (Includes all amendments and changes 12/12/2018).

D4292-23

Standard Test Method for Determination of Vibrated Bulk Density of Calcined Petroleum Coke

C749-15(2020)

Standard Test Method for Tensile Stress-Strain of Carbon and Graphite

C769-15(2020)e1

Standard Test Method for Sonic Velocity in Manufactured Carbon and Graphite Materials for Use in Obtaining an Approximate Value of Young´s Modulus (Includes all amendments and changes 12/3/2020).

C816-15(2020)e1

Standard Test Method for Sulfur Content in Graphite by Combustion-Iodometric Titration Method (Includes all amendments and changes 12/7/2020).

C559-16(2020)

Standard Test Method for Bulk Density by Physical Measurements of Manufactured Carbon and Graphite Articles

C561-23

Standard Test Method for Ash in a Graphite Sample

C577-19

Standard Test Method for Permeability of Refractories

C611-21

Standard Test Method for Electrical Resistivity of Manufactured Carbon and Graphite Articles at Room Temperature

C625-15(2021)

Standard Practice for Reporting Irradiation Results on Graphite

C651-20

Standard Test Method for Flexural Strength of Manufactured Carbon and Graphite Articles Using Four-Point Loading at Room Temperature

C695-21

Standard Test Method for Compressive Strength of Carbon and Graphite

C709-09

Standard Terminology Relating to Manufactured Carbon and Graphite (Withdrawn 2017)

C747-23

Standard Test Method for Moduli of Elasticity and Fundamental Frequencies of Carbon and Graphite Materials by Sonic Resonance

E11-22

Standard Specification for Woven Wire Test Sieve Cloth and Test Sieves

E132-17

Standard Test Method for Poisson´s Ratio at Room Temperature

E228-22

Standard Test Method for Linear Thermal Expansion of Solid Materials With a Push-Rod Dilatometer

E261-16(2021)

Standard Practice for Determining Neutron Fluence, Fluence Rate, and Spectra by Radioactivation Techniques

E639-78(2002)

Standard Test Method for Measuring Total-Radiance Temperature of Heated Surfaces Using a Radiation Pyrometer (Withdrawn 2011)

E1461-13(2022)

Standard Test Method for Thermal Diffusivity by the Flash Method

D7219-19

Standard Specification for Isotropic and Near-isotropic Nuclear Graphites

C838-16(2023)

Standard Test Method for Bulk Density of As-Manufactured Carbon and Graphite Shapes

C1179-21

Standard Test Method for Oxidation Mass Loss of Manufactured Carbon and Graphite Materials in Air