ASTM D5191-18

5.1 Vapor pressure is a very important physical property of volatile liquids.

5.2 The vapor pressure of gasoline and gasoline-oxygenate blends is regulated by various government agencies.

5.3 Specifications for volatile petroleum products generally include vapor pressure limits to ensure products of suitable volatility performance.

5.4 This test method is more precise than Test Method D4953, uses a small sample size (1 mL to 10 mL), and requires about 7 min to complete the test.

1.1 This test method covers the use of automated vapor pressure instruments to determine the total vapor pressure exerted in vacuum by air-containing, volatile, liquid petroleum products, including automotive spark-ignition fuels with or without oxygenates and with ethanol blends up to 85 % (volume fraction) (see Note 1). This test method is suitable for testing samples with boiling points above 0 °C (32 °F) that exert a vapor pressure between 7 kPa and 130 kPa (1.0 psi and 18.6 psi) at 37.8 °C (100 °F) at a vapor-to-liquid ratio of 4:1. Measurements are made on liquid sample sizes in the range from 1 mL to 10 mL. No account is made for dissolved water in the sample.

1.2 This test method is suitable for calculation of the dry vapor pressure equivalent (DVPE) of gasoline and gasoline-oxygenate blends by means of a correlation equation (see Eq 1 in 14.2). The calculated DVPE very closely approximates the dry vapor pressure that would be obtained on the same material when tested by Test Method D4953.

1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.4 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.