ASTM D5827-09(2015)

4.1 This test method provides for the qualitative and quantitative determination of common anions in engine coolant in the milligrams per litre to low percent range and requires only a few millilitres or microlitres of sample per test, with results available in less than 30 min. Acceptable levels of chloride and other anions vary with manufacturer's blending specifications and applicable ASTM minimum or maximum specifications.

1.1 This test method covers the chemical analysis of engine coolant for chloride ion by high-performance ion chromatography (HPIC). Several other common anions found in engine coolant can be determined in one chromatographic analysis by this test method.

1.2 This test method is applicable to both new and used engine coolant.

1.3 Coelution of other ions may cause interferences for any of the listed anions. In the case of unfamiliar formulations, identification verification should be performed by either or both fortification and dilution of the sample matrix with the anions of interest.

1.4 Analysis can be performed directly by this test method without pretreatment, other than dilution, as required by the linear ranges of the equipment. Table 1 indicates several applicable anions and approximate detection limits.